刘建明,男,博士,教授,硕士生导师
河南省教育厅学术技术带头人
河南省高等学校创新团队带头人
河南省高等学校青年骨干教师
Email: jmliu@htu.cn and jmliu1982@163.com
教育与工作经历:
2000.9-2004.7 鲁东大学化学与材料科学院 学士
2004.9-2009.6 中国科学院兰州化学物理研究所硕博连读 博士
2009.7-至今,化学化工学院,副教授,教授
主讲课程:
物理化学
物理化学实验
研究领域与兴趣:
1.均相催化及其反应机理研究
2. 有机合成方法学
近年来主持的主要科研项目:
国家自然科学基金面上项目:基于新型氧化偶联反应合成氮杂环化合物的研究,项目编号:21573057,2016.01-2019.12,66万元
国家自然科学基金青年项目:羰化串联反应合成氮杂环化合物的研究,项目编号:21103044,2012.01-2014.12,25万元。
河南省高校科技创新团队支持计划:精细化学品的清洁合成及其机理研究, 17IRTSTHN001,2017.01-2018.12,100万元。
教育部高等学校学科点专项科研基金:串联反应合成含羰基化合物的研究,20114104120003,2012.01-2015.11,4万元。
中国博士后科学基金特别资助项目:非贵金属催化合成含氮杂环化合物的新策略,2015T80770,2015.07-2017.06,15万元。
中国博士后科学基金面上资助项目:基于C-H键活化的氧化羰基化反应的研究,2014M552005,2014.07-2016.06,5万元。
校优秀青年科学基金:配位介导的绿色氧化偶联研究,2016.11-2019.11,15万元。
代表性论文:
28. Yuanyuan Yue*, Huibin Shao, Zhixian Wang, Ke Wang, Le Wang, Kelei Zhuo,Jianming Liu*.Elemental Sulfur-Incorporated Cyclizations of Pyrrolidines Leading to Thienopyrroles, The Journal of Organic Chemistry, 2020, DOI:10.1021/acs.joc.0c01363.
27. Peizheng Zhao,* Ke Wang, Yuanyuan Yue, Junli Chao, Yaqing Ye, Qinghu Tang, Jianming Liu*. Copper-Catalyzed Aerobic Oxidative Amination of Indole Derivatives via Single-Electron Transfer, ChemCatChem,2020, 12, 3207–3211.
26. Jianming Liu,* Zhixian Wang, Ke Wang, Dong Liu, Yan Yang, Junjun Fan, Kelei Zhuo, Yuanyuan Yue*.Elemental Sulfur-Promoted [2+3+1] Annulation for Synthesis of Functionalized Thiochromeno[2,3-b]indoles from Indole Derivatives, Asian Journal of Organic Chemistry, 2020, 9, 929-932.
25. Jianming Liu,* Yanyan Zhang, Yuanyuan Yue, Zhixian Wang, Huibin Shao, Kelei Zhuo, Qingzhang Lv,* Zhiguo Zhang.* Metal-Free Dehydrogenative Double C-H Sulfuration To Access Thieno[2,3 b]indoles Using Elemental Sulfur, The Journal of Organic Chemistry, 2019, 84, 12946-12959.
24.Huibin Shao, Xiaopei Wang, Yanyan Wang, Yuanyuan Yue, Ke Wang, Qinghu Tang,* Jianming Liu.* BF3⋅Et2O-Promoted Aerobic Bromination of Heteroarenes with LiBr as the Bromination Sources, ChemistrySelect, 2019, 4, 8942-8945.
23.Jianming Liu,* Xuyang Yan, Yuanyuan Yue, Shufang Zhao, Jia Zhang, Yangyang Sun, Kelei Zhuo.* CO2-Promoted C=N Bond Cleavage of Amidines Leading to Multi-substituted Pyridines, Advanced Synthesis & Catalysis, 2018, 360, 2638-2643.
22. Jianming Liu,* Xuyang Yan, Na Liu, Yanyan Zhang, Shufang Zhao, Xiaopei Wang, Kelei Zhuo, Yuanyuan Yue.* Elemental Sulfur Accelerated the Reactivity of the 3-Position of Indole for the Construction of Chromeno[2,3-b]indoles, Organic Chemistry Frontiers, 2018, 5, 1034-1038.
21. Yanyan Zhang, Yuanyuan Yue, Xiaopei Wang, Ke Wang, Yixiao Lou, Meihuan Yao, Kelei Zhuo, Qingzhang Lv,* Jianming Liu.* DMSO-Promoted Metal-Free Aerobic Oxidation of Heterobenzylic Methylene to Prepare N-Heterocyclic Ketones, Asian Journal of Organic Chemistry,2018, 7, 2459-2463.
20. Jianming Liu,* Shufang Zhao, Xuyang Yan, Zhixian Wang, Yanyan Zhang, Peizheng Zhao, Wenhan Fang, Kelei Zhuo, Yuanyuan Yue.* Dual Roles of α, β-Unsaturated Oximes in Copper Catalyzed [3+3] Cyclization: Construction of 2,4,6-Trisubstituted Pyridines, Asian Journal of Organic Chemistry, 2018, 7, 1565-1570.
19. Jianming Liu,* Shanshan Zhao, Weiwei Song, Rong Li, Xinyu Guo, Kelei Zhuo, Yuanyuan Yue.* Silver-Catalyzed Carbon-Phosphorus Functionalization for Polyheterocycle Formation, Advanced Synthesis & Catalysis, 2017, 359, 609- 615.
18. Jianming Liu,* Na Liu, Yuanyuan Yue, Yanyan Wang, Kaige Chen, Jia Zhang, Shufang Zhao, Kelei Zhuo.* Practical Synthesis of Chromeno[2,3-b]indole Skeleton via an Aldehyde Group Insertion/Aromatization Strategy, Chemistry-An Asian Journal, 2017, 12, 401-404.
17.Jianming Liu,* Yanyan Wang, Yuanyuan Yue, Na Liu, Jian Zhang, Shufang Zhao, Qinghu Tang,* Kelei Zhuo. N-Methylpyrrolidin-2-one-Promoted Formation of Functional Esters through C-O Bond Cleavage, European Journal of Organic Chemistry, 2017, 2641-2647.
16. Jianming Liu,* Shanshan Zhao, Xuyang Yan, Yanyan Zhang, Shufang Zhao, Kelei Zhuo, Yuanyuan Yue.* Elemental-Sulfur-Promoted C(sp3)-H Activation of Methyl Heteroarenes Leading to Thioamides, Asian Journal of Organic Chemistry, 2017, 6, 1764-1768.
15. Yuanyuan Yue,* Yangyang Sun, Shufang Zhao, Xuyang Yan, Rong Li, Yaru Shi, Kelei Zhuo, Jianming Liu.* Chloroacetate Promotes and Participates in the Oxidative Annulation of Pyridines/Isoquinoline by Using Oxygen as the Oxidant, Chemistry-An Asian Journal, 2016, 11, 3339-3344.
14. Jianming Liu,* Weiwei Song, Yuanyuan Yue, Ren Liu, Hong Yi, Kelei Zhuo and Aiwen Lei.* Pd(OAc)2/S=PPh3 Accelerated Activation of gem-Dichloroalkenes for the Construction of 3-Arylchromones, Chemical Communication, 2015, 51, 17576-17579.
13. Jianming Liu, Xin Zhang, Hong Yi, Chao Liu, Ren Liu, Heng Zhang, Kelei Zhuo,* Aiwen Lei.* Chloroacetate-Promoted Selective Oxidation of Heterobenzylic Methylenes under Copper Catalysis, Angewandte Chemie International Edition,2015, 54, 1261-1265.
12. Jianming Liu,* Xin Zhang, Lijun Shi, Muwen Liu, Yuanyuan Yue, Fuwei Li,* Kelei Zhuo.* Base-Promoted Synthesis of Coumarins from Salicylaldehydes and Aryl-substituted 1, 1-Dibromo-1-alkenes under Transition-Metal-Free Conditions, Chemical Communication, 2014, 50, 9887-9890.
11. Jianming Liu,# Hong Yi,# Xin Zhang, Chao Liu, Ren Liu, Guoting Zhang, Aiwen Lei.* Copper-Catalysed Oxidative Csp3-H Methylenation to Terminal Olefins Using DMF, Chemical Communication, 2014, 50, 7636-7638.
10. Yuanyuan Yue, # Yuanli Zhang, # Weiwei Song, Xin Zhang, Jianming Liu,* Kelei Zhuo.* Manganese Dioxide-Mediated Oxidative Coupling of 1, 3-Dicarbonyl Compounds with α, β-Unsaturated Ketones: Direct Access to 3, 4-Dicarbonyl Substituted Furans, Advanced Synthesis & Catalysis, 2014, 356, 2459-2464.
9. Jianming Liu, Ningfei Zhang, Yuanyuan Yue, Dong Wang, Yuanli Zhang, Xin Zhang, Kelei Zhuo.* A Simple and Efficient Approach to 2-Alkynylbenzofurans under Mild Copper(I)-Catalyzed Conditions, RSC Advances, 2013, 3, 3865-3868.
8. Jianming Liu,* Ningfei Zhang, Yuanyuan Yue, Guihua Liu, Ren Liu, Yuanli Zhang, Kelei Zhuo.* One-Pot Synthesis of Benzimidazo[1,2-f]phenanthridines by Cascade Palladium-Catalyzed N-Arylation and Intramolecular C-H Coupling, European Journal of Organic Chemistry, 2013, 7683-7687.
7. Jianming Liu, Muwen Liu, Yuanyuan Yue, Ningfei Zhang, Yuanli Zhang, Kelei Zhuo.* Construction of the Flavones and Aurones through Regioselective Carbonylative Annulation of 2-Bromophenols and Terminal Alkynes, Tetrahedron Letters, 2013, 54, 1802-1807.
6. Jianming Liu, Muwen Liu, Yuanyuan Yue, Meihuan Yao, Kelei Zhuo.* Environmental Friendly Azide-Alkyne Cycloaddition Reaction of Azides, Alkynes, and Organic Halides or Epoxides in Water: Efficient “Click” Synthesis of 1, 2, 3-Triazole Derivatives by Cu Catalyst, Chinese Journal of Chemistry, 2012, 30, 644-650.
5. Jianming Liu, Rongzhao Zhang, Shoufeng Wang, Wei Sun*, Chungu Xia*. A General and Efficient Copper Catalyst for the Double Carbonylation Reaction. Organic Letters, 2009, 11, 1321-1324 (cited by Synfacts, 2009, 6, 662).
4.Jianming Liu, Xingao Peng, Wei Sun*, Yongwei Zhao, and Chungu Xia*. Magnetically Separable Pd Catalyst for Carbonylative Sonogashira Coupling Reactions for the Synthesis of α, β-Alkynyl Ketones. Organic Letters, 2008, 10, 3933-3936.
3. Jianming Liu, Wei Sun*, Shuzhan Zheng, Chungu Xia*. Pd/C/PPh3: An Efficient and Simple Catalyst System for Double Carbonylation Reaction. Chinese Journal of Chemistry, 2009, 27, 623-627.
2. Jian-Ming Liu, Xin-Gao Peng, Jian-Hua Liu, Shu-Zhan Zheng, Wei Sun*, Chun-Gu Xia*. Synthesis of 2-Oxazolidinones by Salen-Co-Complexes Catalyzed Oxidative Carbonylation of β-Amino Alcohols. Tetrahedron Letters, 2007, 48, 929-932.
1. Jianming Liu, Wei Sun, Shuzhan Zheng, Chungu Xia. Efficient Synthesis of Oxazolidin-2-one via (Chitosan-Schiff Base)cobalt(II)-catalyzed Oxidative Carbonylation of 2-Aminoalkan-1-ols. Helvetica Chimica Acta, 2007, 90, 1593-1598.
荣誉与奖励:
河南省教育厅学术技术带头人
河南省高等学校骨干教师
骨干教师
河南省优秀博士后研究人员
研究生优秀指导教师
优秀青年科研创新人才
中国科学院朱李月华博士奖